CAS Number 1141757-83-6


Tris-PCz has a tri-carbazole back-boned structure joined at the 3 and 6 positions. The highly-conjugated carbazoles makes Tris-PCz electron-rich, which is widely used as a hole-transport layer material in TADF-OLED devices.
Due to its electron-rich nature, Tris-PCz can form exciplexes with electron-deficient materials (such as B4PyPPM) in highly-efficient OLED devices with TADF characteristics.
Tris-PCz has a high triplet energy (ET = 2.7 eV), so it is also frequently used as an exciton block layer material to effectively prevent the excitons' energy from being transferred (to the donor or acceptor) to achieve high fluorescence quantum efficiency.
| CAS number | 1141757-83-6 |
|---|---|
| Full name | 9-Phenyl-3,6-bis(9-phenyl-9Hcarbazol-3-yl)-9H-carbazole |
| Chemical formula | C54H35N3 |
| Molecular weight | 725.28 g/mol |
| Absorption | λmax 305 nm in DCM |
| Fluorescence | λmax 415 nm in DCM |
| HOMO/LUMO | HOMO = 5.6 eV, LUMO = 2.1 eV; T1 = 2.7 eV [1] |
| Synonyms | 9,9',9''-Triphenyl-9H,9'H,9''H-3,3':6',3''-tercarbazole |
| Classification / Family | Carbazole derivative, Fluorescent host materials, Phosphorescent host materials, Hole-transport layer materials, Exciton-blocking layer materials, TADF-OLED materials, Organic electronics, Sublimed materials. |
| Purity | Sublimed > 99% (HPLC) |
|---|---|
| Melting point | TGA: >270 °C (0.5% weight loss) |
| Appearance | White crystals/powder |
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