CAS Number 1141757-83-6
Tris-PCz has a tri-carbazole back-boned structure joined at the 3 and 6 positions. The highly-conjugated carbazoles makes Tris-PCz electron-rich, which is widely used as a hole-transport layer material in TADF-OLED devices.
Due to its electron-rich nature, Tris-PCz can form exciplexes with electron-deficient materials (such as B4PyPPM) in highly-efficient OLED devices with TADF characteristics.
Tris-PCz has a high triplet energy (ET = 2.7 eV), so it is also frequently used as an exciton block layer material to effectively prevent the excitons' energy from being transferred (to the donor or acceptor) to achieve high fluorescence quantum efficiency.
CAS number | 1141757-83-6 |
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Full name | 9-Phenyl-3,6-bis(9-phenyl-9Hcarbazol-3-yl)-9H-carbazole |
Chemical formula | C54H35N3 |
Molecular weight | 725.28 g/mol |
Absorption | λmax 305 nm in DCM |
Fluorescence | λmax 415 nm in DCM |
HOMO/LUMO | HOMO = 5.6 eV, LUMO = 2.1 eV; T1 = 2.7 eV [1] |
Synonyms | 9,9',9''-Triphenyl-9H,9'H,9''H-3,3':6',3''-tercarbazole |
Classification / Family | Carbazole derivative, Fluorescent host materials, Phosphorescent host materials, Hole-transport layer materials, Exciton-blocking layer materials, TADF-OLED materials, Organic electronics, Sublimed materials. |
Purity | Sublimed > 99% (HPLC) |
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Melting point | TGA: >270 °C (0.5% weight loss) |
Appearance | White crystals/powder |
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