CAS Number 2251782-13-3
n-DABNA (CAS number 2251782-13-3), N7,N7,N13,N13,5,9,11,15-octaphenyl-5,9,11,15-tetrahydro-5,9,11,15-tetraaza-19b,20b-diboradinaphtho[3,2,1-de:1',2',3'-jk]pentacene-7,13-diamine, can be considered as a structure having a pseudo-pentacene core symmetrically containing boron and nitrogen on the second and fourth rings, decorated with peripheral diphenylamines.
n-DABNA has been demonstrated to be an efficient terminal emitter with high PLQY of about 100% and narrowband emission with an FWHM of 14 nm in toluene. Deep blue device based on v-DABNA as emitting layer shows outstanding EQE of 34.4% and very low efficiency roll-off of 5% at 100 cd m−2.
Comparing with t-DABNA, n-DABNA has relatively longer device lifetime albeit it has a red- shifted peak emission wavelength. n-DABNA has also a planar molecular π framework which makes it prone to excimer formation via π-π intermolecular interaction. For this reason, low doping concentration as low as 1% should be used for higher color purity emission.
CAS number | 2251782-13-3 |
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Chemical formula | C78H54B2N6 |
Molecular weight | 1096.93 g/mol |
Absorption* | λmax 457 nm (in toluene) |
Fluorescence | λem 468 nm (in toluene) |
HOMO/LUMO |
HOMO = 5.4 eV, LUMO = 2.8 eV (ES = 2.64 eV, ET = 2.62 eV) |
Synonyms | γ-DABNA, N7,N7,N13,N13,5,9,11,15-Octaphenyl-5,9,11,15-tetrahydro-5,9,11,15-tetraaza-19b,20b-diboradinaphtho[3,2,1-de:1',2',3'-jk]pentacene-7,13-diamine |
Classification / Family | Triarylamine derivatives, Blue dopant, Multiresonance thermally activated delayed fluorescent (MR-TADF), Narrowband TADF molecule, Sublimed materials. |
Purity | Sublimed* >99% (HPLC) |
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Melting point | TGA: Td = 496 °C (5% weight loss) [5] |
Appearance | Yellow crystals/powder |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.
N7,N7,N13,N13,5,9,11,15-Octaphenyl-5,9,11,15-tetrahydro-5,9,11,15-tetraaza-19b,20b-diboradinaphtho[3,2,1-de:1',2',3'-jk]pentacene-7,13-diamine (n-DABNA) chemical structure, 2251782-13-3
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