ossila材料TPA-DCPP

CAS Number 1803287-94-6

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产品详情

TPA-DCPP (CAS number 1803287-94-6), namely 7,10-bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene is a V-shaped molecule consisting of triphenylamine (TPA) as the donor and 2,3-dicyanopyrazino phenanthrene (DCPP) as the acceptor units.

TPA-DCPP undergoes thermally activated delayed fluorescence (TADF) to emit in the deep red/near-IR region. Nondoped OLED with TPA-DCPP as active layer exhibits a maximum external quantum efficiency (EQE) of 2.1 %, whereas the doped device had an EQE of almost 10 %.

CAS number 1803287-94-6
Chemical formula C54H34N6
Molecular weight 766.89 g/mol
Absorption* λmax 308, 458 nm (in film)
Fluorescence λem 810 nm (in DCM)
HOMO/LUMO HOMO = 5.3 eV, LUMO = 3.52 eV
Synonyms 7,10-Bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene
Classification / Family Triarylamine derivatives, Deep red dopant, NIR TADF materials.


Product Details


Purity >98% (NMR)
Melting point TGA: T≥ 508 oC (5% weight loss), Tg = 165 oC
Appearance Deep red crystals/powder


Chemical Structure


tpa-dcpp, 1803287-94-6
7,10-Bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene (TPA-DCPP) chemical structure, CAS 1803287-94-6

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