CAS Number 1883400-34-7
Available in sublimed grade for highly efficient TADF-OLED devices, 5,6-Bis(4-(9,9-dimethylacridin-10(9H)-yl)phenyl)pyrazine-2,3-dicarbonitrile, CAS No. 1883400-34-7
Ac-CNP, 5,6-bis(4-(9,9-dimethylacridin-10(9H)-yl)phenyl)pyrazine-2,3-dicarbonitrile is a TADF yellow to orange emitter with a simple structure of a low-rigid two cyano groups attached electron-accepting pyrazine unit and two electron-donating phenyl acridine units. The two phenyl units act as bridges to the donor acridines and acceptor pyrazine-2,3-dicarbonitrile to form a bipolar A-π-D electronic structure.
Ac-CNP has high photoluminescence quantum yield (PLQY) of 67% and Ac-CNP based devices with mCP as the TADF host showed a high external quantum efficiency (EQE) of 13.3%.
CAS Number | 1883400-34-7 |
Chemical Formula | C48H36N4 |
Molecular Weight | 696.84 g/mol |
Absorption | λmax 282 nm, 436 nm in toluene |
Fluorescence | λmax 620 nm in toluene |
HOMO/LUMO | HOMO = 5.40 eV, LUMO = 3.10 eV [1] |
Full Name | 5,6-Bis(4-(9,9-dimethylacridin-10(9H)-yl)phenyl)pyrazine-2,3-dicarbonitrile |
Synonyms | 5,6-Bis[4-(9,9-dimethyl-9,10-dihydroacridine)pheny]-2,3-dicyano-pyrazine |
Classification / Family | Acridine derivatives, Pyrazines, TADF yellow to orange dopant, Sublimed small molecules |
Purity | Sublimed* >98.0% (HPLC) |
Melting Point | N/A |
Appearance | Orange powder/crystals |
*Sublimation is a technique used to obtain ultra-pure grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
Device Structure | ITO (110 nm)/NPD (40 nm)/mCP (10 nm)/Ac-CNP:mCP (6wt%, 20 nm)/PPF (10 nm)/TPBi (30 nm)/LiF (0.8 nm)/Al (100 nm) [1] |
Colour |
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Max. EQE | 13.3% |
Max. Current Efficiency | 38.1 cd/A |
Max. Power Efficiency | 26.1 Im/W |
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