CAS Number 1252914-27-4
BD-1 is symmetrically structured with a 3,8-diisopropyl-1,6-diamine-pyrene core, and two dibenzo[b,d]furan and 4-isopropylphenyl peripheral end groups. Four isopropyl alkyl groups not only promotes greater solubility but also prevents the quenching of the excimers.
BD-1 is a fluorescent blue emitter and normally an anthracene derivative 1,2-ADN is selected as effective host for BD-1 for improving the external quantum efficiency (EQE) of fluorescent OLEDs by utilizing triplet–triplet annihilation. Top-emission organic light-emitting diodes (TEOLEDs) utilising BD-1 as the blue emitting layer material without indium tin oxide (ITO) but a silver (Ag) layer demonstrated a high efficiency of 139.9 cd/A/CIEy at a current density of 10 mA/cm2 [1, 2].
CAS number | 1252914-27-4 |
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Chemical formula | C64H56N2O2 |
Molecular weight | 885.14 g/mol |
HOMO/LUMO | HOMO = - 5.52 eV, LUMO = - 2.78 eV |
Chemical name | N1,N6-bis(dibenzo[b,d]furan-4-yl)-3,8-diisopropyl-N1,N6-bis(4-isopropylphenyl)pyrene-1,6-diamine |
Synonyms | BDFDPPDA, NFDIP |
Classification / Family | Pyrene derivatives, Triarylamines, Blue fluorescent emitter, Sublimed materials, Semiconducting small molecules |
Purity | Sublimed* >99.0% (HPLC) |
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Melting point | n.a. |
Appearance | Off-white powder/crystals |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.
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