CAS Number 1296229-26-9
mCPPO1 has a bipolar character with an electron rich 1,3-di(9H-carbazol-9-yl)benzene core unit and an electron deficient diphenylphosphine oxide attachment.
mCPPO1 is an extended family member of mCP with a higher glass transition temperature (Tg = 114.7 °C), and can be used as a phosphorescent host material for blue, green and red organic light emitting diodes. The bipolar charge transport properties of mCPPO1 can effectively balance holes and electrons in the emitting layer, improving device performance.
CAS number | 1296229-26-9 |
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Full name | 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole |
Chemical formula | C42H29N2OP |
Molecular weight | 608.67 g/mol |
Absorption | λmax 324 nm, 338 nm (in DCM) |
Phosphorescene | λmax 361 nm (in DCM) |
HOMO/LUMO | HOMO 6.13 eV, LUMO 2.64 eV [1] |
Synonyms | [9-[3-(9H-Carbazol-9-yl)phenyl]-9H-carbazol-3-yl]diphenylphosphine oxide |
Classification / Family | Carbazole derivatives, TADF Light-emitting diodes, Organic electronics, PHOLEDs host materials, Sublimed materials. |
Purity | >99.0% (HPLC) |
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Melting point | Tg = 114.7 °C |
Appearance | White powder/crystals |
Device structure | ITO (70 nm)/4wt% ReO3:mCP (30 nm)/mCP (10 nm)/10wt% (HFP)2Ir(mpic):mCPPO1 (30 nm)/TSPO1 (10 nm)/8wt%Rb2CO3:mCP (30 nm)/Al (100 nm) [3] |
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Colour |
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Max Current Efficiency | 27.2 cd/A |
Max. Power Efficiency | 25.9 lm W-1 |
Max. EQE | 21.4% |
Device structure | ITO (50 nm)/PEDOT(CH8000, 60 nm)/TAPC(20 nm)/mCP(10 nm)/mCPPO1:3wt% Ir(dfpypy)dpm (25 nm)/TSPO1(35 nm)/LiF(1 nm)/Al (200 nm) [4] |
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Colour |
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Max Current Efficiency | 20.4 cd/A |
Max. Power Efficiency | 24.7 lm W-1 |
Device structure | ITO/PEDOT:PSS (45 nm)/TFB (40 nm)/R-QDs:G-QDs* (18 nm, 1:9)/ZnMgO (40 nm)/Al (2 nm)/IZO (60 nm)/HATCN (20 nm)/TAPC (40 nm)/mCP (5 nm)/Firpic:mCPPO1 (30 nm)/TmPyPB (30 nm)/LiF (1 nm)/Al (100 nm) [5] |
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Colour |
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Max. Power Efficiency | 20.31 lm W-1 |
Max. EQE | 26.02% |
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