CAS Number 1268460-37-2
Hex-Ir(phq)3, tris[2-(4-n-hexylphenyl)quinoline)]iridium(III), has three phenylquinoline ligands chelated to the iridium centre. Different to Ir(phq)3,The hexyl chain attached to the benzene ring makes Hex-Ir(phq)3 highly soluble in common organic solvents for easy device fabrication and large-area solution processing, i.e. spin-coating or inkjet printing.
Hex-Ir(phq)3 is a phosphorescent orange to red emitting and slight red-shifted in emission while compared to Ir(phq)3.
CAS number | 1268460-37-2 |
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Chemical formula | C63H66IrN3 |
Molecular weight | 1057.43 g/mol |
Absorption | λmax 323 nm (dichloromethane) |
Photoluminescence | λem 583 nm (dichloromethane) |
HOMO/LUMO | HOMO = 4.9 eV, LUMO = 2.8 eV [1] |
Chemical name | Tris[2-(4-n-hexylphenyl)quinoline)]iridium(III) |
Synonyms | Hex-Ir(phq)3 |
Classification / Family | Iridium complex, Orange to red phosphorescent materials, Blue dopant materials, Electron transport materials, Sublimed materials, Semiconducting small molecules |
Purity | Sublimed >99.0% (HPLC) |
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Melting point | > 260 °C (0.5% weight loss) |
Appearance | Red powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials.
Device structure | ITO/PEDOT:PSS/TFB/PVK:PBD:TPD:Hex-Ir(phq)3 (57:24:9:10)/TPBI/Al [1] |
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Colour |
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Max. Luminance | 17,910 cd/m2 |
Current Efficiency @100 cd/m2 | 14.5 cd/A |
Power Efficiency @100 cd/m2 | 7.7 Im/W |
Device structure | ITO/PEDOT:PSS/TFB/PVK:PBD:TPD:Hex-Ir(phq)3 (53:24:9:14)/TPBI/Al [1] |
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Colour |
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Max. Luminance | 12,950 cd/m2 |
Current Efficiency @100 cd/m2 | 14.9 cd/A |
Power Efficiency @100 cd/m2 | 9.9 Im/W |
Device structure | ITO (130 nm)/PEDOT:PSS (30 nm)/TFB (20 nm)/ICTRZ-1:12wt% Hex-Ir(phq)3 (70 nm)/ZnO NPs (10 nm)/PEIE (20 nm)/PMA (10 nm)/TFB (20 nm)/ICTRZ-1:12wt% Hex-Ir(phq)3 (70 nm)/ZnO NPs (10 nm)/PEIE (20 nm)/Al (100 nm) [2] |
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Colour |
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Max. EQE | 22.8% |
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