ossila材料Hex-Ir(phq)3

CAS Number 1268460-37-2

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Hex-Ir(phq)3.jpg

Hex-Ir(phq)3.jpg

产品详情

Hex-Ir(phq)3, tris[2-(4-n-hexylphenyl)quinoline)]iridium(III), has three phenylquinoline ligands chelated to the iridium centre. Different to Ir(phq)3,The hexyl chain attached to the benzene ring makes Hex-Ir(phq)3 highly soluble in common organic solvents for easy device fabrication and large-area solution processing, i.e. spin-coating or inkjet printing.

Hex-Ir(phq)3 is a phosphorescent orange to red emitting and slight red-shifted in emission while compared to Ir(phq)3.

General Information


CAS number 1268460-37-2
Chemical formula C63H66IrN3
Molecular weight 1057.43 g/mol
Absorption λmax 323 nm (dichloromethane)
Photoluminescence λem 583 nm (dichloromethane)
HOMO/LUMO HOMO = 4.9 eV, LUMO = 2.8 eV [1]
Chemical name Tris[2-(4-n-hexylphenyl)quinoline)]iridium(III)
Synonyms Hex-Ir(phq)3
Classification / Family Iridium complex, Orange to red phosphorescent materials, Blue dopant materials, Electron transport materials, Sublimed materials, Semiconducting small molecules

Product Details


Purity Sublimed >99.0% (HPLC)
Melting point > 260 °C (0.5% weight loss)
Appearance Red powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials.

Chemical Structure


Hex-Irphq3, 1268460-37-2
Chemical structure of Tris[2-(4-n-hexylphenyl)quinoline)]iridium(III) (Hex-Ir(phq)3), CAS 1268460-37-2

Device Structure(s)


Device structure ITO/PEDOT:PSS/TFB/PVK:PBD:TPD:Hex-Ir(phq)(57:24:9:10)/TPBI/Al [1]
Colour red light emitting device Red
Max. Luminance 17,910 cd/m2
Current Efficiency @100 cd/m2 14.5 cd/A
Power Efficiency @100 cd/m2 7.7 Im/W
Device structure ITO/PEDOT:PSS/TFB/PVK:PBD:TPD:Hex-Ir(phq)(53:24:9:14)/TPBI/Al [1]
Colour red light emitting device Red
Max. Luminance 12,950 cd/m2
Current Efficiency @100 cd/m2 14.9 cd/A
Power Efficiency @100 cd/m2 9.9 Im/W
Device structure ITO (130 nm)/PEDOT:PSS (30 nm)/TFB (20 nm)/ICTRZ-1:12wt% Hex-Ir(phq)3 (70 nm)/ZnO NPs (10 nm)/PEIE (20 nm)/PMA (10 nm)/TFB (20 nm)/ICTRZ-1:12wt% Hex-Ir(phq)3 (70 nm)/ZnO NPs (10 nm)/PEIE (20 nm)/Al (100 nm) [2]
Colour red light emitting device Red
Max. EQE 22.8%

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