ossila材料PPF

CAS Number 911397-27-8

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产品详情

PPF contains an electron donating dibenzo[b,d]furan core and two electron deficient diphenylphosphine oxide units. Due to their electron deficient nature, both PPF and PPT can be used as electron transport layer materials, and in some cases, to form exciplex with electron deficient donors, i.e. TAPC as emitting layer materials in TADF-OLED devices.

PPF shows a high triplet energy (ET = 3.1 eV) and it also can be used as host material for effective triplet excitons confinement in the emissive layer. PPF could also be used as exciton blocking layer material.

General Information


CAS number 911397-27-8
Full name 2,8-Bis(diphenyl-phosphoryl)-dibenzo[b,d]furan
Chemical formula C36H26O3P2
Molecular weight 568.54 g/mol
Absorption λmax 300 nm in DCM
Fluorescence λem 440 nm in DCM
HOMO/LUMO HOMO = 6.7 eV, LUMO = 2.7 eV (ET = 3.1 eV) [1]
Synonyms
  • DFPO
  • DBFPO
  • Dibenzo[b,d]furan-2,8-diylbis(diphenylphosphine oxide)
Classification / Family Dibenzofuran derivatives, Organic electronics, Electron-transport layer materials (ETL), Phosphorescent host materials, Fluorescent host materials, TADF-OLEDs, Organic long persistent luminescence, Sublimed materials.

Product Details


Purity Sublimed: >99.0% (HPLC)
Melting point 253 °C (dec.)
Appearance White powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure


ppf, 911397-27-8
Chemical structure of 2,8-bis(diphenylphosphoryl)dibenzo[b,d]furan (PPF), CAS 911397-27-8

Device Structure(s)


Device structure ITO (50 nm)/HAT-CN (10 nm)/TAPC (50 nm)/CCP (10 nm)/PPF:TMCz-BO (20 nm)/PPF (10 nm)/B3PyPB (30 nm)/Liq (1 nm)/Al (100 nm) [1]
Colour blue light emitting device Blue
Max. EQE 20.7%
Device structure ITO (50 nm)/TAPC (70 nm)/CDBP (10 nm)/6 wt% CCX-II:PPF (20 nm)/PPF (10 nm)/BmPyPhB (30 nm)/Liq (1 nm)/Al (80 nm) [2]
Colour blue light emitting device Blue
Max. EQE 25.9%
Max. Current Efficiency 41.1 cd/A
Max. Power Efficiency 35.9 lm/W
Device structure ITO (50 nm)/HAT-CN (10 nm)/α-NPD (50 nm)/CCP (5 nm)/ 6 wt % DPAc-INN-1:PPF (20 nm)/PPF (10 nm)/TPBi (50 nm)/Liq (1 nm)/Al (100 nm) [3]
Colour blue light emitting device Blue
Max. EQE 12.8%
Max. Current Efficiency 24.2 cd/A
Max. Power Efficiency 18.1 lm/W
Device structure ITO/HAT-CN (10 nm)/a-NPD (40 nm)/CCP (5 nm)/18 wt% MFAc-PPM:PPF (20 nm)/PPF (10 nm)/TPBi (30 nm)/Liq (1 nm)/Al (100 nm) [4]
Colour blue light emitting device Blue
Max. EQE 20.4%
Max. Current Efficiency 41.7 cd/A
Max. Power Efficiency 37.2 lm/W

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