CAS Number 18920-16-6


UGH3, 1,3-bis(triphenylsilyl)benzene, is an isomer to UGH-2, 1,4-bis(triphenylsilyl)benzene.
UGH3 is an ultrahigh energy gap (4.40 eV) organosilicon compounds and a weak electron-transport-type host for highly efficient blue PHOLEDs. UGH3 has a high triplet energy (ET=3.1 eV) and can also be used as a host material to dilute exciplex, to enhance TADF-OLED optical and electrical device performance. Having a deep HOMO energy level (7.2 eV), UGH3 can also be used as an effective hole blocking layer material.
Both UGH2 and UGH3 have low glass transition temperatures (Tg) below 100 °C. BSB, 4,4'-di(triphenylsilyl)-biphenyl, however, offers better morphology of OLED device films for higher device performance and stability with higher Tg at 100 °C.
| CAS number | 18920-16-6 |
|---|---|
| Chemical formula | C42H34Si2 |
| Molecular weight | 594.89 g/mol |
| Absorption | λmax 265 nm in THF |
| Fluorescence | λem 418 nm |
| HOMO/LUMO | HOMO = 7.20 eV, LUMO = 2.80 eV, ET =3.1 eV [1] |
| Full chemical name | 1,3-Bis(triphenylsilyl)benzene |
| Synonyms | UGH-3 |
| Classification / Family | Phosphorescent blue host material, Hole blocking materials, Sublimed materials |
| Purity | Sublimed >99.0% (HPLC) |
|---|---|
| Melting point | Tg = 46 °C, TGA: >280 °C (0.5% weight loss) |
| Appearance | White powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials.
| Device structure | ITO (70 nm)/NPB (40 nm)/mCP (7.5 nm)/UGH3:FIrpic:Bt2Ir(acac) (14%, 0.3%) (30 nm)/UGH3 (5 nm)/Bphen (50 nm)/LiF (1 nm)/Al (120 nm) [2] |
|---|---|
| Colour |
White |
| Max. Current Efficiency | 47.5 cd/A |
| Max. EQE | 18.9 % |
| Max. Power Efficiency | 36.6 Im/W |
| Device structure | ITO (70 nm)/NPB (40 nm)/mCP (7.5 nm)/UGH3:mCP (7:3):14 wt%FIrpic:0.3 wt% Bt2Ir(acac) (30 nm)/UGH3 (5 nm)/Bphen (50 nm)/LiF (1 nm)/Al (120 nm) [2] |
|---|---|
| Colour |
White |
| Max. Current Efficiency | 47.6 cd/A |
| Max. EQE | 18.9 % |
| Max. Power Efficiency | 40.9 Im/W |
| Device structure | ITO/NPB (40 nm)/TSBPA (10 nm)|TSBPA:PO-T2T 1:1 in 50 vol % UGH-3 (40 nm)|POT2T (50 nm)|LiF (1 nm)|Al (100 nm) [3] |
|---|---|
| Colour |
Green |
| Max. EQE | 19.2 % |
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