CAS Number 913738-04-2
HBL material to significantly improve device operational lifetimes, 2,8-Di(9H-carbazol-9-yl)dibenzo[b,d]thiophene, CAS No. 913738-04-2, Sublimed ≥99.0%
DCzDBT, also referred to as mCBT, is a carbazole-based bipolar host material containing two carbazole and one dibenzothiophene units for blue thermally activated delayed fluorescent (TADF) devices achieving excellent external quantum efficiencies (EQE).
With a wide bandgap, DCzDBT has also been used as hole blocking layer (HBL) material to replace BAlq to significantly improve device operational lifetimes.
CAS number | 913738-04-2 |
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Chemical formula | C36H22N2S |
Molecular weight | 514.64 g/mol |
Absorption | λmax 293 nm (in DCM) |
Fluorescence | λem 385 nm (in DCM) |
HOMO/LUMO | HOMO = 5.71 eV, LUMO = 2.19 eV [1] |
Full chemical name | 2,8-Di(9H-carbazol-9-yl)dibenzo[b,d]thiophene |
Synonyms | mCBT, ZDZ, 2,8-Bis(9H-carbazol-9-yl)dibenzothiophene, 9,9'-(2,8-Dibenzothiophenediyl)bis-9H-carbazole |
Classification / Family | Carbazole derivatives, TADF host materials, Sublimed materials |
Purity | Sublimed >99.0% (HPLC) |
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Melting point | TGA >350 °C (0.5% weight loss) |
Appearance | Off-white powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
Device structure | ITO/HATCN (10 nm)/NPD (40 nm)/TrisPCz/10% PtN'1N-tBu:mCBP (25nm)/DCzDBT (8 nm)/BPyTP (40 nm)/LiF (1 nm)/Al (100 nm) [2] |
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Colour |
Sky-blue ![]() |
Max. EQE | 17.8% |
Device structure | ITO (40 nm)/HATCN (10 nm)/NPD (40 nm)/Tris-PCz (10 nm)/20% PtNON:mCBP (10 nm)/10% PtNON:mCBP (4 nm)/2% TBPe:mCBP (2 nm)/10% PtNON:mCBP (4 nm)/6% PtNON:mCBP (10 nm)/DCzDBT (8 nm)/ BPyTP (40 nm)/LiF (1 nm)/AL (100 nm) [3] |
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Colour |
Sky-blue ![]() |
Max. EQE | 18% |
Device structure | ITO (50 nm)/HATCN (7 nm)/TAPC (75 nm)/2CzPN 6 wt% DCzDBT (20 nm)/TmPyPB (50 nm)/LiF (1.5 nm)/Al (100 nm) |
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Colour |
Sky-blue ![]() |
Max. Current Efficiency | 10.72 cd/A |
Max. EQE | 18.5 % |
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