ossila材料TXO-PhCz

CAS Number 1623010-64-9

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产品详情

High PLQY efficiency and purity, 2-phenyl-4'-carbazole-9H-thioxanthen-9-one-10,10-dioxide, CAS No. 1623010-64-9, Sublimed ≥99.0%


TXO-PhCz is a TADF green emitter with a typical D-A structure consisting with electron withdrawing thioxanthone and electron-donating phenylcarbazole units.

The D-A moieties of TXO-PhCz is angularly linked to provide effective separation of electron densities of the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) in a single molecule.

Small ΔEST of 73 meV for TXO-PhCz is observed resulting efficient reversed intersystem crossing (RISC) and then high photoluminescence quantum yield (PLQY) efficiency.

General Information


CAS number 1623010-64-9
Chemical formula C31H19NO3S
Molecular weight 485.55g/mol
Absorption λmax396 nm (in toluene)
Fluorescence λem522 nm(in toluene)
HOMO/LUMO HOMO = 5.78 eV, LUMO = 3.58 eV [1]
Full chemical name 2-phenyl-4'-carbazole-9H-thioxanthen-9-one-10,10-dioxide
Synonyms TXO-PhCz
Classification / Family Thioxanthone Derivatives, TADF green emitter materials, Sublimed materials

Product Details


Purity Sublimed >99.0% (HPLC)
Melting point TGA: >350 °C(0.5% weight loss)
Appearance Yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure


txo-phcz, 1623010-64-9
Chemical Structure of 2-phenyl-4'-carbazole-9H-thioxanthen-9-one-10,10-dioxide (TXO-PhCz), CAS#1623010-64-9.

Device Structure(s)


Device structure ITO/ZnO (20 nm)/Cs2CO3 (5 nm)/BPhen (40 nm)/mCBP:10wt% TXO-PhCz (30 nm)/TAPC (40 nm)/MoO3 (10 nm)/Al (90 nm) [2]
Colour Green green light emitting device
Max. Current Efficiency 53.9 cd/A
Max. EQE 16.4 %
Max. Power Efficiency 35.6 Im/W
Device structure ITO (150 nm)/PEDOT (20 nm)/TAPC (20 nm)/mCP (10 nm)/TXO-PhCz:TPBI (5 wt%) (30 nm)/TmPyPB (65 nm)/LiF (0.9 nm)/Al (100 nm) [3]
Colour Green green light emitting device
Max. Current Efficiency 71.9 cd/A
Max. EQE 23.2 %
Max. Power Efficiency 45.2 Im/W
Device structure ITO/ZnO (25 nm)/Cs2CO3(7 nm)/Alq3 (30 nm)/T2T (10 nm)/TXO-PhCz:mCBP (10% 30 nm)/TAPC (50 nm)/MoO3 (10 nm)/Al (100 nm) [4]
Colour Green green light emitting device
Max. Current Efficiency 28.1 cd/A
Max. EQE 9.8 %
Max. Power Efficiency 16.1 Im/W

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