CAS Number 1469700-26-2
5TCzBN is another sky-blue emitter from the cabzolyl benzonitrile (CBN) family that is used in TADF-OLED devices with great performance.
Acting as an encapsulation shell to the luminophore in 5TCzBN, tert-butyl units are believed to reduce the singlet–triplet splitting (ΔEST) of the compounds, which gives rise to a more efficient reverse intersystem crossing (RISC) process by effectively separating the neighbouring molecules.
CAS number | 1469700-26-2 |
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Full name | 2,3,4,5,6-pentakis(3,6-di-tert-butyl-9H-carbazol-9-yl)benzonitrile |
Chemical formula | C107H120N6 |
Molecular weight | 1490.13 g/mol |
Absorption* | λmax 420 nm in toluene |
Fluorescence | λem 480 nm in toluene |
HOMO/LUMO | HOMO = 5.75 eV, LUMO = 2.74 eV, T1 = 2.60 eV [1] |
Classification / Family | Carbazole, Phthalonitrile, TADF materials, Blue dopant materials, Sublimed materials |
* Measurable with an optical spectrometer
Purity | Sublimed* >99.0% (1H NMR) |
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Melting point | Tg = 325 °C (lit.) |
Appearance | Yellow powder/crystals |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials.
Device structure | ITO/HATCN (5 nm)/NPB (30 nm)/TCTA (10 nm)/mCBP:5TCzBN (20 wt%) (30 nm)/DpyPA:Liq (1:1, 30 nm)/LiF (0.5 nm)/Al (150 nm) [2] |
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Colour |
Sky-blue ![]() |
Max. EQE | 21.2% |
Max. Power Efficiency | 56.1 Im/W |
Device structure | ITO/HATCN (5 nm)/NPB (40 nm)/TCTA (10 nm)/30 wt% 5TCzBN: DMIC-TRZ (30 nm)/B3PyMPM (40 nm)/LiF (1 nm)/Al (150 nm) [3] |
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Colour |
Blue ![]() |
Max. EQE | 19.2% |
Max. Power Efficiency | 33.8 Im/W |
Device structure | ITO/HATCN/NPB (30 nm)/TCTA (10 nm)/5TCzBN: mCBP (30 nm)/DPyPA:Liq (1:1, 30 nm)/Al/LiF (0.5 nm) [4] |
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Colour |
Blue ![]() |
Max. EQE | 21.3% |
Half-life Time | 12,873h @ 100cd/m2 |
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