ossila材料5TCzBN

CAS Number 1469700-26-2

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5TCzBN.jpg

5TCzBN.jpg

产品详情

5TCzBN is another sky-blue emitter from the cabzolyl benzonitrile (CBN) family that is used in TADF-OLED devices with great performance.

Acting as an encapsulation shell to the luminophore in 5TCzBN, tert-butyl units are believed to reduce the singlet–triplet splitting (ΔEST) of the compounds, which gives rise to a more efficient reverse intersystem crossing (RISC) process by effectively separating the neighbouring molecules.

General Information


CAS number 1469700-26-2
Full name 2,3,4,5,6-pentakis(3,6-di-tert-butyl-9H-carbazol-9-yl)benzonitrile
Chemical formula C107H120N6
Molecular weight 1490.13 g/mol
Absorption* λmax 420 nm in toluene
Fluorescence λem 480 nm in toluene
HOMO/LUMO HOMO = 5.75 eV, LUMO = 2.74 eV, T1 = 2.60 eV [1]
Classification / Family Carbazole, Phthalonitrile, TADF materials, Blue dopant materials, Sublimed materials

* Measurable with an optical spectrometer

Product Details


Purity Sublimed* >99.0% (1H NMR)
Melting point Tg = 325 °C (lit.)
Appearance Yellow powder/crystals

* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials.

Chemical Structure


1469700-26-2, 5tczbnChemical Structure of 2,3,4,5,6-pentakis(3,6-di-tert-butyl-9H-carbazol-9-yl)benzonitrile (5TCzBN), CAS 1469700-26-2.

Device Structure(s)


Device structure ITO/HATCN (5 nm)/NPB (30 nm)/TCTA (10 nm)/mCBP:5TCzBN (20 wt%) (30 nm)/DpyPA:Liq (1:1, 30 nm)/LiF (0.5 nm)/Al (150 nm) [2]
Colour Sky-blue blue light emitting device
Max. EQE 21.2%
Max. Power Efficiency 56.1 Im/W
Device structure ITO/HATCN (5 nm)/NPB (40 nm)/TCTA (10 nm)/30 wt% 5TCzBN: DMIC-TRZ (30 nm)/B3PyMPM (40 nm)/LiF (1 nm)/Al (150 nm) [3]
Colour Blue blue light emitting device
Max. EQE 19.2%
Max. Power Efficiency 33.8 Im/W
Device structure ITO/HATCN/NPB (30 nm)/TCTA (10 nm)/5TCzBN: mCBP (30 nm)/DPyPA:Liq (1:1, 30 nm)/Al/LiF (0.5 nm) [4]
Colour Blue blue light emitting device
Max. EQE 21.3%
Half-life Time 12,873h @ 100cd/m2

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