ossila材料5CzBN

CAS Number 1469700-24-0

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5TCzBN.jpg

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产品详情


5CzBN, penta-carbazolylbenzonitrile, is sterically hindered due to the five bulky electron-donating carbazolyl groups on the benzene ring struggling for space. It is a light-blue TADF fluorescence emitter widely used for highly efficient TADF-OLED devices.

General Information


CAS number 1469700-24-0
Full name 2,3,4,5,6-penta(carbazol-9-yl)benzonitrile
Synonyms 5CzCN, 2,3,4,5,6-penta(9H-carbazol-9-yl)benzonitrile
Chemical formula C67H40N6
Molecular weight 929.1 g/mol
Absorption λmax 325 nm, 348 nm and 420 nm in DCM
Fluorescence λem 488 nm in toluene
HOMO/LUMO HOMO = 5.55 eV, LUMO = 2.74 eV, T1 = 2.68 eV [1]
Classification / Family Carbazole, Phthalonitrile, TADF materials, Blue dopant materials, Sublimed materials

Product Details


Purity Unsublimed >98%; Sublimed >99.0% (1H NMR)
Melting point Tg = 318 °C (lit.)
Appearance Yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure


5czbn, 1469700-24-0Chemical Structure of 2,3,4,5,6-penta(carbazol-9-yl)benzonitrile (5CzBN), CAS 1469700-24-0.

Device Structure(s)


Device structure ITO/HATCN (5 nm)/NPB (30 nm)/TCTA (10 nm)/mCBP:5CzBN (20 wt%) (30 nm)/DpyPA:Liq (1:1, 30 nm)/LiF (0.5 nm)/Al (150 nm) [2]
Colour Blue blue light emitting device
Max. EQE 16.7%
Max. Power Efficiency 40.0 Im/W
Device structure ITO (100 nm)/HATCN (10 nm)/TrisPCz (30 nm)/mCBP (10 nm)/15wt%-5CzBN:mCBP (30 nm)/T2T (10 nm)/BPyTP2 (40 nm)/LiF (0.8 nm)/Al (100 nm) [3]
Colour Blue blue light emitting device
Max. EQE 18.0%
Max. Power Efficiency 49.9 Im/W

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