ossila材料BCBP

CAS Number 858131-70-1

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BCBP, host material for blue, green, red phosphorescent dopants for highly efficient OLED devices

High-purity (>99.0%) and available online for priority dispatch, BCBP, Sublimed ≥99%, CAS No. 858131-70-1


2,2'-bis(4-(carbazol-9-yl)phenyl)-biphenyl (BCBP) has a bridged biphenyl structure with two electron rich carbazolyl pendant moieties. The bridged structure is believed to enhance the conjugation and raise the HOMO energy level, facilitating hole-injection and leading to low turn-on voltages in organic photoelectroluminescent devices.

Comparing with 4,4′-(bis(9-carbazolyl))biphenyl (CBP), a well known host material, BCBP is thermally more stable with a high glass transition temperature (Tg) of 173 °C, while CBP has a relatively low Tg of 69 °C.

Carbazolyl groups are largely embedded in both fluorescent and phosphorescent host materials because of their higher triplet energy levels and higher hole mobility. Like the rest of the family members such as CDBP and mCBP, BCBP is commonly used as host material for blue, green, red phosphorescent dopants for highly efficient OLED devices.

General Information


CAS number 858131-70-1
Full name 2,2'-bis(4-(carbazol-9-yl)phenyl)-biphenyl
Chemical formula C48H32N2
Molecular weight 636.78 g/mol
Absorption* λmax 325 nm in DCM
Fluorescence λem 373 nm in DCM
HOMO/LUMO HOMO = 6.1 eV, LUMO = 2.6 (Eg = 3.5 eV; ET = 2.8 eV)
Synonyms 2,2'-bis(4-carbazolylphenyl)-1,1'-biphenyl
Classification / Family Organic electronics, Hole transport layer materials (HTL), Fluorescent and phosphorescent host materials, TADF-OLEDs, Sublimed materials.

* Measurable with a USB spectrometer

Product Details


Purity Sublimed* >99.0% (HPLC)
Melting point

Tg = 173 °C (lit.)

TGA: >330 °C (0.5% weight loss)

Colour White powder/crystals

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