CAS Number 858131-70-1
High-purity (>99.0%) and available online for priority dispatch, BCBP, Sublimed ≥99%, CAS No. 858131-70-1
2,2'-bis(4-(carbazol-9-yl)phenyl)-biphenyl (BCBP) has a bridged biphenyl structure with two electron rich carbazolyl pendant moieties. The bridged structure is believed to enhance the conjugation and raise the HOMO energy level, facilitating hole-injection and leading to low turn-on voltages in organic photoelectroluminescent devices.
Comparing with 4,4′-(bis(9-carbazolyl))biphenyl (CBP), a well known host material, BCBP is thermally more stable with a high glass transition temperature (Tg) of 173 °C, while CBP has a relatively low Tg of 69 °C.
Carbazolyl groups are largely embedded in both fluorescent and phosphorescent host materials because of their higher triplet energy levels and higher hole mobility. Like the rest of the family members such as CDBP and mCBP, BCBP is commonly used as host material for blue, green, red phosphorescent dopants for highly efficient OLED devices.
CAS number | 858131-70-1 |
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Full name | 2,2'-bis(4-(carbazol-9-yl)phenyl)-biphenyl |
Chemical formula | C48H32N2 |
Molecular weight | 636.78 g/mol |
Absorption* | λmax 325 nm in DCM |
Fluorescence | λem 373 nm in DCM |
HOMO/LUMO | HOMO = 6.1 eV, LUMO = 2.6 (Eg = 3.5 eV; ET = 2.8 eV) |
Synonyms | 2,2'-bis(4-carbazolylphenyl)-1,1'-biphenyl |
Classification / Family | Organic electronics, Hole transport layer materials (HTL), Fluorescent and phosphorescent host materials, TADF-OLEDs, Sublimed materials. |
* Measurable with a USB spectrometer
Purity | Sublimed* >99.0% (HPLC) |
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Melting point |
Tg = 173 °C (lit.) TGA: >330 °C (0.5% weight loss) |
Colour | White powder/crystals |
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