CAS Number 1374770-41-8
9-(3-(9H-Carbazol-9-yl)-5-(phenylsulfonyl)phenyl)-9H-carbazole (mCPSOB) is an ambipolar host thermally activated delayed fluorescence (TADF) material containing two electron-donating carbazole groups and one electron-accepting diphenylsulfonyl group.
mCPSOB has a high energy level of the triplet state (3.02 eV), which suppresses triplet exciton quenching and results in higher external quantum efficiency (EQE). Higher triplet energy level also makes it ideal as a host material for blue/deep blue dopants.
Compared to mCP, mCPSOB has a higher glass transition temperature (Tg = 140 °C). In return, this can prevent mCPSOB from crystallising during operation and reduces the possibility of phase separation - thus significantly improving device thermal and morphological stability.
CAS number | 1374770-41-8 |
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Full name | 9-(3-(9H-Carbazol-9-yl)-5-(phenylsulfonyl)phenyl)-9H-carbazole |
Chemical formula | C36H24N2O2S |
Molecular weight | 548.65 g/mol |
HOMO/LUMO |
HOMO 5.8 eV, LUMO 2.5 eV; ES = 2.93 eV, ET = 3.02 eV [1] |
Synonyms | 3,5-Di(carbazol-9-yl)-1-phenylsulfonylbenzene |
Classification / Family | Carbazole derivatives, Light-emitting diodes, Organic electronics, TADF blue/green host materials, Ambipolar materials, Sublimed materials. |
Purity | Sublimed >99.0% (HPLC) |
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Melting point |
TGA > 200 °C (0.5% weight loss) Tg = 140 °C |
Appearance | Off-white powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
Device structure | ITO/MoO3 (15 nm)/Poly-TriCZ (50 nm)/mCPSOB:4CzIPN (25 nm)/TPBi (60 nm)/LiF (1 nm)/Al (100 nm) [1] |
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Colour |
Green ![]() |
Current Efficiency@10 cd/m2 | 80.6 cd/A |
EQE@10 cd/m2 | 26.5% |
Power Efficiency@10 cd/m2 | 79 lm W-1 |
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