ossila材料TXO-TPA

CAS Number 1623010-63-8

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产品详情

TXO-TPA has an ambipolar D-A type structure with TXO as the electron-accepting and triphenylamine (TPA) as the electron-donating unit. The twice-oxidised thiophene on TXO moiety can greatly enhance the electron-accepting ability as the channel for higher electron mobility. On the other hand, electron-rich TPA is used as the channel for higher hole mobility.

TXO-TPA is commonly used as a red dopant material in TADF-OLED devices. This is due to its high device performance capabilities with high external quantum efficiency (EQE).

General Information


CAS number 1623010-63-8
Full name 2-[4-(diphenylamino)phenyl]-10,10-dioxide-9H-thioxanthen-9-one
Chemical formula C31H21NO3S
Molecular weight 487.57 g/mol
Absorption λmax 310, 375 nm in film
Fluorescence λem 625 nm in film
HOMO/LUMO HOMO 5.37 eV, LUMO 3.49 eV [1]
Synonyms 9-H-Thioxanthen-9-one-10,10-dioxide-triphenylamine
Classification / Family Thioxanthone derivatives, Organic electronics, TADF-OLEDs, TADF red dopant materials, Sublimed materials.

Product Details


Purity Sublimed >99.0% (HPLC)
Melting point TGA: >250 °C (0.5% weight loss)
Appearance Orange powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure



txo-tpa, 1623010-63-8
Chemical structure of TXO-TPA, 2-[4-(diphenylamino)phenyl]-10,10-dioxide-9H-thioxanthen-9-one, CAS 1623010-63-8

Device Structure(s)


Device structure ITO/PEDOT (30 nm)/TAPC (20 nm)/5 wt%TXO-TPA:mCP (35 nm) /TmPyPB (55 nm)/LiF(0.9 nm)/Al [1]
Colour Yellow yellow light emitting device
Current Efficiency@100 cd/m2 43.3 cd/A
EQE@100 cd/m2 18.5 %
Power Efficiency@100 cd/m2 47.4 lm W-1
Device structure ITO/PEDOT (20 nm)/TAPC (30 nm)/TXO-TPA (0.5 nm)/4P-NPB* (0.5 nm)/mCP (10 nm)/TmPyPB (50 nm)/LiF (0.9 nm)/Al (100 nm) [2]
Colour White white light emitting device
Max. Current Efficiency 10.5 cd/A
Max. EQE 4.4%
Max. Power Efficiency 8.9 lm W-1

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