CAS Number 1477511-57-1
PXZ-DPS possesses a structure of a weak electron-accepting diphenylsulfone and strong electron-donating acridine moieties. It is used as a TADF green emitter or dopant, and has a small ΔEST of less than 0.1 eV, a short lifetime of less than 3.1 µs.
Like DMAC-DPS, PXZ-DPS has high photo-luminescence quantum yields (PLQY) in devices even with the change of host materials. It is an ideal candidate for applications in green TADF-OLED devices with biploar charge-transporting capability.
CAS number | 1477511-57-1 |
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Full name | 10-(4-(4-(10H-Phenoxazin-10-yl)phenylsulfonyl)phenyl)-10H-phenoxazine |
Chemical formula | C36H24N2O4S |
Molecular weight | 580.65 g/mol |
Absorption | n/a |
PL | λem 507 nm in toluene |
HOMO/LUMO | HOMO = 5.59 eV, LUMO = 2.79 eV; T1=2.74 eV, ΔEST = 0.08 eV [1] |
Synonyms | DPS-PXZ |
Classification / Family | Acridine derivatives, TADF green emitter, TADF green host materials, Sublimed materials |
Purity | Sublimed >99.0% (HPLC) |
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Melting point | TGA > 220 °C (0.5% weight loss) |
Appearance | Off-white powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
Device structure | ITO/a-NPD (30 nm)/TCTA (20 nm)/CzSi (10 nm)/PXZ–DPS:DPEPO (20 nm)/DPEPO (10 nm)/TPBI (30 nm)/LiF (1 nm)/Al [2] |
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Colour |
Green ![]() |
Max EQE | 17.6% |
Device structure | ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2] |
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Colour |
Green ![]() |
Max EQE | 19.3% |
Max. Power Efficiency | 48.5 lm W-1 |
Device structure | ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:PhCzTRz:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2] |
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Colour |
Green ![]() |
Max EQE | 24% |
Max. Power Efficiency | 71.4 lm W-1 |
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