CAS Number 19205-19-7
N,N'-Dimethylquinacridone (DMQA) is a green dopant material used in OLEDs. Highly stable and longer-lifetime OLED devices have been achieved by using DMQA as the dopant to a double host (aminoanthracene and Alq3). It is believed that DMQA can prevent excimer formation, thus prolonging the the lifetime of the devices.
By using DMQA as a green dopant, very high efficiency OLEDs with a luminance of greater than 88,000 cd/m2, EQE of 5.4% and current efficiency of 21.1 cd/A have been achieved. DMQA has also been used in green light photodetectors for practical applications, such as photo sensors and chemical sensors.
CAS number | 19205-19-7 |
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Chemical formula | C22H16N2O2 |
Molecular weight | 340.37 g/mol |
Absorption | λmax 294 nm, 510 nm (in THF) |
Fluorescence | λem 523 nm (in THF) |
HOMO/LUMO | HOMO = 5.35 eV; LUMU = 3.17 eV [1] |
Synonyms |
|
Classification / Family | Green dopant materials, OLEDs, Photodetectors, Organic electronics |
Purity | >99% (sublimed) |
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Melting point | 286 °C (dec.)(lit.) |
Colour | Red powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
Device structure | ITO/CuPc (15 nm)/NPB (60 nm)/Alq3:0.4 wt.% DMQA (37.5 nm)/Alq (37.5 nm)/MgAg (200 nm) [2] |
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Colour |
Green ![]() |
Luminance | 1,322 cd/m2 |
Current Efficiency | 6.61 cd/A |
Lifetime (T1/2) | 7,500 hours |
Device structure | ITO (150 nm)/a-NPB (60 nm)/Alq3: 1 wt.% C545T*:0.75 wt.% DMQA (30 nm)/Alq3 (30 nm)/LiF (0.8 nm)/Al (150 nm) [3] |
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Colour |
Green ![]() |
Max. EQE | 6.7% |
Max. Luminance | 84,900 cd/m2 |
Max. Current Efficiency | 23.4 cd/A |
Device structure | (ITO)/2-TNATA (5 nm)/NPB (40 nm)/CBP:6 wt.% Ir(ppy)3:0.5 wt.% DMQA (30 nm)/Bphen (10 nm)/Alq3 (20nm)/LiF (0.5 nm)/Al (100 nm) [4] |
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Colour |
Green ![]() |
Max. EQE | 1.85 |
Max. Current Efficiency | 7.08 cd/A |
Max. Power Efficiency | 4.03 lm/W |
Device structure | ITO (80 nm)/NPB (40 nm)/ADN:0.6 wt.% C545T*:1.2 wt.% DMQA (30 nm)//Alq3 (30 nm)/LiF (1 nm)/Al(100 nm) [5] |
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Colour |
Green ![]() |
Luminance @ 50 mA/cm2 | 4,750 cd/m2 |
Current Efficiency @ 50 mA/cm2 | 9.5 cd/A |
Device structure | ITO/NPB (60nm)/ADN:Alq (9:1):0.8 wt.% DMQA (20nm)/BPhen (10nm)/Alq3 (30nm)/LiF (1nm)/Al (200nm) [6] [@20 mA/cm2: 14.7 cd/A) |
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Colour |
Green ![]() |
Current Efficiency @ 20 mA/cm2 | 14.7 cd/A |
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