UGH2, ETL and HBL material for organic electronic devices
TADF host material for blue-emitting dopants in highly-efficient blue PhOLEDs, CAS No. 40491-34-7 / 18856-08-1, Sublimed ≥99.0%
1,4-Bis(triphenylsilyl)benzene, known as UGH-2, is one of the well-known TADF host materials for blue-emitting dopants (such as FIrPic) in highly-efficient blue PhOLEDs. This is due to its wide energy gap (4.4 eV) and high triplet energy (ET = 3.5 eV).
With a very deep HOMO energy level (HOMO = 7.2 eV), UGH-2 also works as an electron-transport (ETL) and hole-blocking layer (HBL) material.
General Information
CAS number
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40491-34-7; 18856-08-1
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Full name
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1,4-Bis(triphenylsilyl)benzene
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Chemical formula
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C42H34Si2
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Molecular weight
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594.89 g/mol
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Absorption
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λmax 265 nm in DCM
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Fluorescence
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λem 298 nm in DCM
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HOMO/LUMO
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HOMO = 7.2 eV, LUMO = 2.8 eV (ET = 3.5 eV)
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Synonyms
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UGH2, 1,4-Phenylenebis(triphenylsilane)
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Classification / Family
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Organic electronics, Hole-blocking layer materials (HBL), TADF blue host materials, Blue PhOLEDs, TADF-OLEDs, Sublimed materials.
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Product Details
Purity
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Sublimed: >99.0% (TGA)
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Melting point
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TGA: 358.61 °C (5% weight loss)
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Colour
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White powder/crystals
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*Sublimation is a technique used to obtain ultra pure-grade chemicals, see the sublimed materials.
Chemical Structure
Chemical structure of UGH-2, CAS
40491-34-7 / 18856-08-1
Device Structure(s)
Device structure
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ITO/MoOx (5 nm)/NPB (40 nm)/TCTA (5 nm)/3% Y-Pt :mCP(20 nm)/8% FIrpic:UGH2 (20 nm)/TAZ (40 nm)/LiF (0.5 nm)/Al (100 nm) [1]
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Colour
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White
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Max. Current Efficiency
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29.8 cd/A
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Max. EQE
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10.3%
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Max. Power Efficiency
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19.7 lm W-1
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Device structure
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ITO/MoOx (5 nm)/NPB (40 nm)/mCP(10 nm)/2% Y-Pt:8% FIrpic:UGH2 (20 nm)/TAZ (40 nm)/LiF (0.5 nm)/Al (100 nm) [1]
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Colour
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White
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Max. Current Efficiency
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28.5 cd/A
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Max. EQE
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9.1%
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Max. Power Efficiency
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21.3 lm W-1
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Device structure
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ITO/MoO x (5 nm)/NPB (40 nm)/4% Y-Pt :TCTA (20 nm)/8%FIrpic:mCP(10 nm)/8% FIrpic:UGH2 (10 nm)/BAlq (40 nm)/LiF (0.5 nm)/Al (100 nm) [1]
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Colour
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White
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Max. Current Efficiency
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45.6 cd/A
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Max. EQE
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16.0%
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Max. Power Efficiency
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35.8 lm W-1
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Device structure
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ITO/TAPC (30 nm)/TCTA (10 nm)/CzSi (3 nm)/CzSi doped with 4 wt% of 2c* (25 nm)/UGH2 doped with 4 wt% of 2c*(3 nm)/UGH2 (2 nm)/TmPyPB (50 nm)/LiF (0.8 nm)/Al (150 nm) [2]
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Colour
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Blue
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Max. Current Efficiency
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22.3 cd/A
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Max. EQE
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11%
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Max. Power Efficiency
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16.7 Im/W
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Device structure
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(ITO)/a-NPD (30 nm)/TCTA (20 nm)/CzSi (3 nm)/CzSi doped with 6 wt% [Ir(fppz)2(dfbdp)] (35 nm)/UGH2 doped with 6 wt% [Ir(fppz)2(dfbdp)] (3 nm)/UGH2 (2 nm)/BCP (50 nm)/Cs2CO3 (2 nm)/Ag (150 nm) [3]
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Colour
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Blue
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Max. Current Efficiency
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11.4 cd/A
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Max. EQE
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11.9%
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Max. Power Efficiency
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7.9 Im/W
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Device structure
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ITO/2-TNATA (30 nm)/TAPC (30 nm)/TCTA (10 nm)/mCP:8 wt.% (F2CF3Ch2ppy)2Ir(pic-N-oxide)* (20 nm)/UGH2:15 wt.% (F2CF3Ch2ppy)2Ir(pic-N-oxide) (10 nm)/BAlq (40 nm)/LiF (1 nm)/Al (100 nm) [4]
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Colour
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Blue
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Max. Current Efficiency
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36.1 cd/A
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Max. EQE
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23.3%
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Max. Power Efficiency
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17.3 Im/W
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Device structure
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ITO/TAPC (40 nm)/mCP (10 nm)/UGH2:10 wt.% FIrpic (20 nm)/ 3TPYMB (40 nm)/LiF (1 nm)/Al (100 nm) [5]
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Colour
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Blue
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Max. Current Efficiency
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49 cd/A
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Max. EQE
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23%
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Max. Power Efficiency
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31.6 Im/W
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