CAS Number 936355-01-0


NPNPB, full name N,N'-diphenyl-N,N'-di-[4-(N,N-diphenyl-amino)phenyl]benzidine, is one of the family members of triarylamines. NPNPB is electron rich and can be used as an electron-transport layer material for OLEDs and perovskite solar cells. Due to its electron-donating nature, NPNPB is also used together with electron acceptors (such as PO-T2T) to form exciplexes in highly-efficient thermally activated delayed fluorescence OLEDs.
NPNPB is also introduced into the interface between ITO and NPB as a buffer layer. This works to smooth the ITO surface and lower the barrier to hole-charge injection.
| CAS number | 936355-01-0 |
|---|---|
| Full name | N,N'-diphenyl-N,N'-di-[4-(N,N-diphenyl-amino)phenyl]benzidine |
| Chemical formula | C60H46N4 |
| Molecular weight | 823.03 g/mol |
| Absorption | λmax 324 nm in THF |
| Fluorescence | λem 450 nm in THF |
| HOMO/LUMO | HOMO = 5.1 eV, LUMO = 3.0 eV [1] |
| Synonyms | N,N'-Bis[4-(diphenylamino)phenyl]-N,N'-diphenyl-3,3'-biphenyldiamine |
| Classification / Family | Triarylamines Organic electronics, Hole-transport layer materials (HTL), Hole-injection layer materials (HIL), TADF materials, Sublimed materials. |
| Purity | Sublimed: > 99% (HPLC) |
|---|---|
| Melting point | TGA: >370 °C (0.5% weight loss) |
| Appearance | Yellow powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
| Device structure | ITO/NPNPB (60 nm)/NPB (10 nm)/TCTA (10 nm)/BIQMCz*: Ir(piq)3 (4 wt%) (30 nm)/BAlq (30 nm)/LiF (1 nm)/Al (100 nm) [1] |
|---|---|
| Colour |
Red |
| Max. Power Efficiency | 26.2 lm W-1 |
| Max. EQE | 23.3% |
| Max. Current Efficiency | 27.1 cd/A |
| Device structure | ITO/NPNPB (60 nm)/NPB (10 nm)/DMPPP:2 wt% 1bb* (30 nm)/BAlq (20 nm)/LiF (1 nm)/Al [2] |
|---|---|
| Colour |
Blue |
| Max. Power Efficiency | 4.23 lm W-1 |
| Max. EQE | 5.2% |
| Max. Current Efficiency | 5.38 cd/A |
| Device structure | ITO/NPNPB (60 nm)/NPB (10 nm)/DMPPP:2 wt% 2bb* (30 nm)/BAlq (20 nm)/LiF (1 nm)/Al [2] |
|---|---|
| Colour |
Blue |
| Max. Power Efficiency | 4.23 lm W-1 |
| Max. EQE | 4.72% |
| Max. Current Efficiency | 5.87 cd/A |
| Device structure | ITO/NPNPB (60 nm)/NPB (10 nm)/DMPPP:2 wt% 2bb* (30 nm)/BAlq (20 nm)/LiF (1 nm)/Al [2] |
|---|---|
| Colour |
Blue |
| Max. Power Efficiency | 4.23 lm W-1 |
| Max. EQE | 4.72% |
| Max. Current Efficiency | 5.87 cd/A |
| Device structure | ITO/NPNPB: 10% MoO3 (5 nm)/NPNPB (80 nm)/NPB (10 nm)/DMPPP: 5% TSTA* (25 nm)/BAlq2 (20 nm)/LiF (1 nm)/Al (100 nm) [3] |
|---|---|
| Colour |
Blue |
| Max. Power Efficiency | 5.7 lm W-1 |
| Max. EQE | 10.2% |
| Max. Current Efficiency | 12.3 cd/A |
| Device structure | ITO/NPNPB: 10% MoO3 (5 nm)/NPNPB (80 nm)/NPB (10 nm)/DMPPP: 5% TSMA* (25 nm)/BAlq2 (20 nm)/LiF (1 nm)/Al (100 nm) [3] |
|---|---|
| Colour |
Blue |
| Max. Power Efficiency | 8.7 lm W-1 |
| Max. EQE | 8.9% |
| Max. Current Efficiency | 10.3 cd/A |
| Device structure | ITO/NPNPB (50 nm)/NPB (10 nm)/DMPPP: PPIE (5 wt%) (25 nm)/BAlq (20 nm)/LiF (1 nm)/Al (100 nm) [4] |
|---|---|
| Colour |
Blue |
| Max. Power Efficiency | 4.8 lm W-1 |
| Max. EQE | 8.1% |
| Max. Current Efficiency | 10.0 cd/A |
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