CAS Number 910058-11-6


Sublimed and unsublimed grades are available for NPB-DPA, N,N'-Bis[4-(diphenylamino)phenyl]-N,N'-di(1-naphthyl)benzidine, CAS No. 910058-11-6, Sublimed ≥99.0%, Unsublimed ≥98.0%
NPB-DPA, full name N,N'-Bis[4-(diphenylamino)phenyl]-N,N'-di(1-naphthyl)benzidine, is a derivative of triarylamines. It has a skeleton of two joined triarylamines with two diphenylamine as pending units. It is electron-rich and commonly used as a hole-injection layer (HIL) material in OLED devices.
NPB is normally used as a hole-transporting layer (HTL) material. In comparison, NPB-DPA is inserted between an ITO anode and a HTL to effectively modify the cathode surface and facilitate the collection of the holes to the electrode.
Like NPB-DPA, NPB's sister compound NPNPB is also commonly used as the buffer layer between a HTL and an anode to lower the barrier of the hole injections.
| CAS number | 910058-11-6 |
|---|---|
| Full name | N,N'-Bis[4-(diphenylamino)phenyl]-N,N'-di(1-naphthyl)benzidine, N,N’-Bis[4-(diphenylamino)phenyl]-N,N’-di-1-naphthalenyl-[1,1′-biphenyl]-4,4′-diamine |
| Chemical formula | C68H50N4 |
| Molecular weight | 923.18 g/mol |
| Absorption* | λmax 355 nm in DCM |
| Fluorescence | λmax 515 nm in DCM |
| HOMO/LUMO | HOMO = 5.2 eV, LUMO = 1.9 eV [1] |
| Classification / Family | Triarylamines, Hole-transport layer (HTL) materials, Hole-injection layer (HIL) materials, Electron-blocking layer materials, OLED materials, Sublimed materials, Organic electronics. |
* Measurable with an optical spectrometer
| Purity | Sublimed* >99% (HPLC); Unsublimed >98% |
|---|---|
| Melting point | n/a |
| Appearance | Off-white crystal/powder |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials.
| Device structure | ITO/NPB-DPA (60 nm)/TBB (30 nm)/NA-MSBAF*:DSA-Ph (30 nm, 5%)/LG201* (20 nm)/LiF/Al [1] |
|---|---|
| Colour |
Sky-blue |
| Max. Luminance | 11,080 cd/m2 |
| Max. Current Efficiency | 7.67 cd/A |
| Max. EQE | 5.15% |
| Device structure | ITO/NPB-DPA (60 nm)/TBB (30 nm)/NA-SBAF*:DSA-Ph (30 nm, 5%)/LG201* (20 nm)/LiF/Al [1] |
|---|---|
| Colour |
Sky-blue |
| Max. Luminance | 13,020 cd/m2 |
| Max. Current Efficiency | 7.73 cd/A |
| Max. EQE | 4.93% |
| Device structure | ITO/NPB-DPA (60 nm)/TBB (30 nm)/NSBTF*:DSA-Ph (30 nm, 5%)/LG201* (20 nm)/LiF/Al [1] |
|---|---|
| Colour |
Sky-blue |
| Max. Current Efficiency | 7.91 cd/A |
| Max. EQE | 4.76% |
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