CAS Number 141460-19-7


Cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II), also known as N3 Dye, is one of the earliest benchmarked ruthenium complex dyes developed for high-efficiency dye-sensitized solar cells (DSSC). Since its discovery, it has become the paradigm of heterogeneous charge-transfer sensitizer for mesoporous solar cells.
Fully-protonated N3 dye has absorption maxima at 518 nm and 380 nm, with extinction coefficients of 13 K and 13.3 K M−1 cm−1 respectively. Adsorbed onto nanocrystalline TiO2 film, total energy conversion efficiency from light to electricity η of the cell was 10% under AM 1.5 irradiation [1]
| Full name | Cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) |
| Synonyms | N3 Foundation Dye |
| Chemical formula | C26H16N6O8RuS2 |
| Molecular weight | 705.64 |
| CAS number | 141460-19-7 |
| HOMO / LUMO | HOMO = -5.39 eV, LUMO = -2.79 eV |
| Solubility | Ethanol |
| Classification / Family | Transition metal complex, Ruthenium complex, Bipyridyl ligands, Energy materials, Dye-sensitized solar cells DSSC) materials, Donor materials, OPV materials. |
Chemical structure of N3 Dye; Chemical formula: C26H16N6O8RuS2
| Purity | 99% |
| Melting point | >300 °C |
| Appearance | Dark purple powder |
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