CAS Number 6876-37-5
Methylammonium bromide (MABr) is a precursor for the synthesis of organic-inorganic hybrid perovskites for use in FETs, LEDs and PVs.
99.995% (M572)
>99.995% (M571 further purified by recrystallisation of M572)
Methylammonium bromide (MABr) is a precursor of MAPbBr3 perovskites. Having a band gap of 2.3 eV (HOMO 5.68 eV, LUMO 3.38 eV) [1], MAPbBr3 perovskites have been used to tune the band gap of mixed MAPbX3 (where X is the halide I, Br and/or Cl mixtures) [2,3,4,5,6]. For this reason, bromide MAPbBr3 perovskites can be utilised as light absorbers for high-energy photons, and can serve as the front cell in tandem cells. This perovskite can provide a higher open-circuit voltage in perovskite solar cells than the iodide analogue.
High-efficiency solar cells, with a VOC of up to 1.40 V, a fill factor (FF) of 79%, and a PCE of 6.7% have been reported for pure MAPbBr3 perovskite solar cells [1].
It has also been demonstrated that MAPbBr3 nanoplatelets can be employed in light-emitting diodes, exhibiting bright photoluminescence (PL) at 529 nm, with a narrow spectral band and a quantum yield up to 85% [7].
CAS number
6876-37-5
Chemical formula
CH6BrN
Molecular weight
111.97 g/mol
Synonyms
HOMO / LUMO
n.a.
Classification / Family
Organic photovoltaics, Light-emitting diodes, Perovskite precursor materials
Product Details
Purity
Melting point
296 °C
Appearance
White crystals/powder
Chemical Structure
Chemical structure of methylammonium bromide (MABr), CAS No. 6876-37-5
Applications
Device structure
FTO/TiO2/(FAPbI3)0.85(MAPbBr3)0.15/PTAA/Au [8]
Jsc (mA cm-2)
23.3
Voc (V)
0.94
FF (%)
65
PCE
14.2
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