ossila材料o-IDTBR

CAS Number 2077945-91-4

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产品详情

o-IDTBR, CAS number 2077945-91-4, is a small molecule acceptor which demonstrates an acceptor-acceptor–donor–acceptor-acceptor (A-A'–D–A'-A) structure. This consists of an electron-donating ladder-type fused five-member-ring indaceno[1,2-b:5,6-b′]dithiophene (IDT) core with aliphatic n-octyl side chains flanked by two electron withdrawing benzothiadiazole moieties and rhodanine terminated groups.

With a maximum absorption at around 600 – 730 nm and reduced charge recombination losses, o-IDTBR has been widely used as an n-type non-fullerene acceptor (NFA) in polymer organic photovoltaics. Among its useful properties, it shows promising stability under ambient conditions and exhibits outstanding photovoltaic performance.

Using PTB7-Th as the low band-gap donor polymer, mixed acceptors of o-IDTBR and o-IDFBR have demonstrated impressive device performance. An efficiency of 11.0 ± 0.4% and a high open-circuit voltage of 1.03 ± 0.01 has been reported.

Device structure: indium tin oxide (ITO)/ zinc oxide (ZnO)/PCE10:IDTBR:IDFBR (85 ± 5 nm) /molybdenum oxide (MoO3)/Ag [2]

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
85 ± 5 1.03 ± 0.01 17.2 ± 0.1 60 ± 1 11.0 ± 0.4

o-IDTBR is available to buy online in quantities from 100 mg to 1 g (please contact us for larger orders). Larger quantities offer the best value, while smaller quantities may be more suitable for some applications. Eligible orders ship free.

General Information


CAS Number 2077945-91-4
Chemical Formula C72H88N6O2S8
Purity >98% (1HNMR)
Full Name (5Z,5'Z)-5,5'-((7,7'-(4,4,9,9-tetraoctyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b']dithiophene-2,7-diyl)bis(benzo[c][1,2,5]thiadiazole-7,4-diyl))bis(methanylylidene))bis(3-ethyl-2-thioxothiazolidin-4-one)
Molecular Weight 1326.03 g/mol
Absorption λmax 600 – 730 nm (Film)
HOMO/LUMO

HOMO = -5.56 eV

LUMO = -3.93 eV [1]

Melting Point 219 – 221 °C (lit.)
Solubility Chloroform, chlorobezene
Form Dark blue powder/crystals
Synonyms IDTBR
Classification / Family NFAs, n-type non-fullerene electron acceptors, organic semiconducting materials, low band-gap small molecule, small molecular acceptor, organic photovoltaics, polymer solar cells, NF-PSCs

Chemical Structure


EH-IDTBR chemical structure, CAS 2077945-91-4Chemical structure of o-IDTBR, CAS 2077945-91-4

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