CAS Number 2077945-91-4
o-IDTBR, CAS number 2077945-91-4, is a small molecule acceptor which demonstrates an acceptor-acceptor–donor–acceptor-acceptor (A-A'–D–A'-A) structure. This consists of an electron-donating ladder-type fused five-member-ring indaceno[1,2-b:5,6-b′]dithiophene (IDT) core with aliphatic n-octyl side chains flanked by two electron withdrawing benzothiadiazole moieties and rhodanine terminated groups.
With a maximum absorption at around 600 – 730 nm and reduced charge recombination losses, o-IDTBR has been widely used as an n-type non-fullerene acceptor (NFA) in polymer organic photovoltaics. Among its useful properties, it shows promising stability under ambient conditions and exhibits outstanding photovoltaic performance.
Using PTB7-Th as the low band-gap donor polymer, mixed acceptors of o-IDTBR and o-IDFBR have demonstrated impressive device performance. An efficiency of 11.0 ± 0.4% and a high open-circuit voltage of 1.03 ± 0.01 has been reported.
Device structure: indium tin oxide (ITO)/ zinc oxide (ZnO)/PCE10:IDTBR:IDFBR (85 ± 5 nm) /molybdenum oxide (MoO3)/Ag [2]
Thickness (nm) | VOC (V) | JSC (mA cm-2) | FF (%) | PCE (%) |
---|---|---|---|---|
85 ± 5 | 1.03 ± 0.01 | 17.2 ± 0.1 | 60 ± 1 | 11.0 ± 0.4 |
o-IDTBR is available to buy online in quantities from 100 mg to 1 g (please contact us for larger orders). Larger quantities offer the best value, while smaller quantities may be more suitable for some applications. Eligible orders ship free.
CAS Number | 2077945-91-4 |
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Chemical Formula | C72H88N6O2S8 |
Purity | >98% (1HNMR) |
Full Name | (5Z,5'Z)-5,5'-((7,7'-(4,4,9,9-tetraoctyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b']dithiophene-2,7-diyl)bis(benzo[c][1,2,5]thiadiazole-7,4-diyl))bis(methanylylidene))bis(3-ethyl-2-thioxothiazolidin-4-one) |
Molecular Weight | 1326.03 g/mol |
Absorption | λmax 600 – 730 nm (Film) |
HOMO/LUMO |
HOMO = -5.56 eV LUMO = -3.93 eV [1] |
Melting Point | 219 – 221 °C (lit.) |
Solubility | Chloroform, chlorobezene |
Form | Dark blue powder/crystals |
Synonyms | IDTBR |
Classification / Family | NFAs, n-type non-fullerene electron acceptors, organic semiconducting materials, low band-gap small molecule, small molecular acceptor, organic photovoltaics, polymer solar cells, NF-PSCs |
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