Nickel Phosphorus Trisulfide (NiPS3) Powder and Crystal
Nickel phosphorus trisulfide (NiPS3) is a layered quasi-two dimensional antiferromagnetic (AFM) semiconductor (TN=155 K). Nickel phosphorus trisulfide (NiPS3) belongs to the group of 2D layered transition metal phosphorus trichalcogenides (MPX3). Among them, NiPS3 has quite unique physical properties with capability of both p-type and n-type doping for device applications and the smallest bandgap energy (~1.6 eV).
The antiferromagnetic ordering in NiPS3 is persistent down to two-layer nano-structures and is substantially suppressed in the monolayer, unlike the case of Ising-type antiferromagnet FePS3 in which antiferromagnetic ordering maintains down to the monolayer limit. Antiferromagnetic van der Waals material NiPS3 offers a good model system for the XY Hamiltonian or XXZ-type, while FePS3 of anistropic Ising-type and MnPS3 of isotropic Heisenberg-type.
Can be used for preparation of nickel phosphorus trisulfide nanoplates and ultrathin films
Available in quantities of 1 g
≥99.995% purity
Can be used to produce single or few-layer nickel phosphorus trisulfide sheets via mechanical or liquid exfoliation
Small (≥10 mm2) or medium (≥25 mm2) crystals available*
≥99.999% purity
CAS Number | N/A |
Chemical Formula | NiPS3 |
Molecular Weight | 185.86 g/mol |
Bandgap | ~1.6 eV (in bulk) |
Preparation | Synthetic - Chemical Vapour Transport (CVT) |
Structure | Monoclinic |
Electronic Properties | 2D Magnetic semiconductor |
Melting Point | N/A |
Colour | Green |
Synonyms | Nickel phosphosulphide, Nickel thiophosphate, Nickel phosphorous trisulphide |
Classification / Family | 2D layered transition metal phosphorus trichalcogenides (MPX3), Magnetic semiconductor, Antiferromagnet, Nano-electronics, Nano-photonics, Photovoltaic, Materials science |
Form | Purity |
---|---|
Powder | ≥99.995% |
Crystal | ≥99.999% |
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