英国ossila材料PBDB-T (PCE12)

Luminosyn™ Polymers, Materials, OPV Polymers, Semiconducting Polymers

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PBDB-T-大图.png

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产品详情

PBDB-T (PCE12), CAS number 1415929-80-4, is one of the highest-performing donor polymers for OPVs, having reported efficiencies exceeding 12% and a certified efficiency approaching 11%. These efficiencies were achieved when PBDB-T was used in conjunction with recently-reported non-fullerene acceptors (NFAs, including ITIC) in inverted architecture devices. These devices also exhibited excellent thermal stability, making the combination a promising candidate for the proposed 10/10 target of 10% efficiency and 10-year lifetimes.

General Information


Full name Poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(5,5-(1’,3’-di-2-thienyl-5’,7’-bis(2-ethylhexyl)benzo[1’,2’-c:4’,5’-c’]dithiophene-4,8-dione)]
Synonyms PBDB-T, PBDTBDD
Chemical formula (C68H78O2S8)n
CAS number 1415929-80-4
HOMO / LUMO HOMO = -5.33 eV, LUMO = -2.92 eV [3]
Solubility Chloroform and chlorobenzene
Processing solvent Chlorobenzene - M1001A3, Chlorobenzene : Dichlorobenzene (1:1) - M1001A4
Classification / Family

Organic semiconducting materials, Medium band-gap polymers, Organic Photovoltaics, Polymer solar cells, Perovskite solar cells, Hole-transport layer materials, NF-PSCs, All-polymer solar cells (all-pscs).

Chemical Structure


Chemical structure of PBDB-T (PCE12)Chemical structure and product image of PBDB-T (PCE12)

Device Structure(s)

The device structure of the certified devices was ITO / ZnO (30 nm) / PBDB-T:ITIC (100 nm) / MoO3 (10 nm) / Al (100 nm), with PBDB-T:ITIC solution details as follows:

  • Blend ratio: 1:1,
  • Concentration: 20 mg/ml,
  • Solvent: Chlorobenzene
  • Additive: 0.5% Diiodooctane.

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