Hole Injection Layer Materials, Interface Polymers, Materials, Perovskite Interface Materials, Perov
Poly(9,9-dioctylfluorene-alt-N-(4-sec-butylphenyl)-diphenylamine) (TFB), CAS number 220797-16-0, is a triarylamine based semiconductor with a band gap of 3.0 eV (HOMO and LUMO levels of 5.3 eV and 2.3 eV, respectively) and a relatively high hole mobility of 2 ×10-3 cm2 V-1 s-1.
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General Information
CAS Number
220797-16-0
Chemical Formula
(C51H61N)n
Absorption*
λmax 390 nm (in THF)
Fluorescence
λem 295 nm, 435 nm (in THF)
HOMO/LUMO
HOMO = 5.3 eV, LUMO = 2.3 eV
Solvents
THF, Toluene and Chloroform
Synonyms
Poly(9,9-dioctylfluorene-alt-N-(4-sec-butylphenyl)-diphenylamine)
Classification / Family
Hole transport material (HTL), Hole injection material (HIL), Electron blocking material (EBL), OLEDs, Perovskite solar cells, Organic and printed electronics
Product Details
Melting Point
N/A
Colour
Pale yellow powder/fibers
Chemical Structure
Chemical Structure of Poly(9,9-dioctylfluorene-alt-N-(4-sec-butylphenyl)-diphenylamine) (TFB)
Device Structure(s)
Device Structure
ITO (120 nm)/PEDOT:PSS(50 nm)/TFB (5 nm)/PYGTPA* (75 nm)/PEGPF* (10 nm)/Ca (10 nm)/Al (100 nm) [1]
Colour
Deep Blue
Max. luminance
9,242 cd/m2
Max. Current Efficiency
0.85 cd/A
Bias
4.3 V
Device Structure
ITO/c-ZnO (50 nm)/F8BT (80 nm)/MoO3 (10 nm)/Au (50 nm) [2]
ITO/c-ZnO (50 nm)/F8BT (80 nm)/TFB (60 nm)/MoO3 (10 nm)/Au (50 nm) [2]
Colour
Green
Green
Max. luminance
9,370 cd/m2
16,460 cd/m2
Max. Current Efficiency
0.34 cd/A
0.93 cd/A
Bias
~0.60 V
~0.87 V
Device Structure
ITO/ZnO/CsPbI3/TFB (60 nm)/MoO3 (5 nm)/Ag (80 nm) [3]
Colour
Red
Max. Luminance
206 cd/m2
Max. EQE
5.7%
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