Charge Transport Layer Materials, Electron Transport Layer Materials, High Purity Sublimed Materials
Diphenyl-bis[4-(pyridin-3-yl)phenyl]silane, DPPS, has two pyridyl groups attached to the tetra-phyenylsilane. Hence, it is electron-deficient.
Almost considered as an insulator, DPPS is a weak electron-transporting material with a wide bandgap Eg = 4.0 eV. Due to its deep HOMO energy level, DPPS is also used as a hole-blocking layer material in photo-electronic devices.
CAS number | 1152162-74-7 |
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Full name | Diphenyl-bis(4-(pyridin-3-yl)phenyl)silane |
Chemical formula | C34H26N2Si |
Molecular weight | 490.67 g/mol |
Absorption | λmax 251 nm in DCM |
Fluorescence | λem 366 nm in DCM |
HOMO/LUMO | HOMO = 6.5 eV, LUMO = 2.5 (ET = 2.7 eV) |
Synonyms | 3,3'-[(Diphenylsilylene)di-4,1-phenylene]bispyridine |
Classification / Family | Organic electronics, Hole-blocking layer materials (HBL), Electron-transporting layer materials (ETL), TADF-OLEDs, Sublimed materials. |
Purity | Sublimed >99.0% (HPLC) |
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Melting point | TGA: >250 °C (0.5% weight loss) |
Colour | White powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.
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